Nisachol Nerngchamnong, Benjamas Chailap, Pannee Leeladee, Orawon Chailapakul,
Chomchai Suksai, Thawatchai Tuntulani
Two derivatives of p-tert-butylcalix[4]arenes 1 and 2 containing diethyl ester and amidoferrocene units
as cation and anion binding sites, respectively, have been synthesized. Both compounds were isomeric
with different topology for accommodating ions. 1H NMR spectroscopy, cyclic voltammetry, and
square-wave voltammetry were used to study the binding abilities of receptors 1 and 2 toward anions.
Both receptors were found to bind Br and I selectively in the presence of Na+. The electrochemically
oxidized ferrocenium form of para-isomer 2 in the free form was found to sense AcO selectively, but
demonstrated a negative sensing in the presence of Na+. In contrast, the electrochemically oxidized ferrocenium
form of meta-isomer 1 was found to enhance sensing of AcO and Cl in the presence of Na+.
journal homepage: www.elsevier.com/ locate/tetlet
- Emre IŞIKLI'nın 2007'den beri
gelen tercüme tecrübesi,
- İngilizce Endüstri
Mühendisliği, Gazi Üniversitesi, Ankara
- Finans Yüksek Lisans derecesi,
Hofstra Üniversitesi, New York
- 6 Yıl Amerika Birleşik
Devletleri'nde eğitim ve kültürel uyum tecrübesi bulunmaktadır.
- Kitap, altyazı ve makale
çevirileri konusunda yoğunlaşmış; günümüze kadar Mühendislikler, İşletme,
Bankacılık, Muhasebe, Turizm, Tarım ve Hayvancılık, Veterinerlik, Eğitim
Bilimleri, Tarih, Coğrafya, Jeoloji, Tekstil alanlarında pozitif
referanslara sahiptir.


